Chemistry Thermodynamics and Thermochemistry JEE Advanced Previous Years Question Numeric Response
Published on: August 14, 2026

One mole of an ideal gas is taken from a and b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is w s and that along the dotted line path is w d , then the integer closest to the ratio w d / w s is :

A

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The correct answer is:
2

(2)

Process shown by solid line is reversible isothermal

So, work W s = – 4 × 0.5 ln (5.5/0.5) = – 2 ln 11 L atm.

For dotted process (three step irreversible) work done will be

W d = – {4 × 1.5 + 1 × 1 + × 2.5} L atm.

= – {6 + 1 + } L atm. = – L atm.

so, 2.

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