Chemistry Co-ordinatios Compounds General Introduction of Complex Salts and Definitions to be used Subjective Type
Published on: August 14, 2026

1 g of complex [Cr(H 2 O) 5 Cl]Cl 2 .H 2 O was passed through a cation exchanger to produce HCl. The acid liberated was diluted to 1 litre. What will be the molarity of acid solution [Molecular weight of complex = 266.5] ?

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The correct answer is:
0.0075.

(0.0075.)

Sol. 1 mole of complex will give two moles of Cl – ion, i.e. 2 mole HCl

[Cr(H 2 O) 5 Cl]Cl 2 . H 2 O [Cr(H 2 O) 5 Cl] +2 + 2Cl –

1 g

mole of HCl = (for HCl, V.f. = 1 ∴ N = M)

∴ N = = 0.0075.

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