Home Chemistry Co-ordinatios Compounds JEE ADVANCED Previous Year Question Which one of the following has a square plan…
Chemistry Co-ordinatios Compounds JEE ADVANCED Previous Year Question Single Correct MCQ
Published on: August 14, 2026

Which one of the following has a square planar geometry? (At. no. Co = 27, Ni = 28, Fe = 26, Pt = 78)

A
[NiCl 4 ] 2–
B
[PtCl 4 ] 2–
C
[CoCl 4 ] 2–
D
[FeCl 4 ] 2–

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Text Solution

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The correct answer is:
B

In 4-coordinate complex of platinum (Pt II ), the four ligands are arranged about the central platinum ion(II) in a square planar geometry (dsp 2 ) because of higher CFSE of 5d 8 configuration.

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