An octahedral complex with molecular composition M.5NH 3 .Cl.SO 4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO 3 solution and the solution of B gives white precipitate with BaCl 2 solution. The type of isomerism exhibited by the complex is:
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The two possible isomers for the given octahedral complex are 
and 
. They respectively give chloride ion (indicated by precipitation with 
) and 
ion (indicated by precipitation with 
). Hence the type of isomerism exhibited by the complex is ionization isomerism.
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