exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of
in the paramagnetic and diamagnetic states respectively are
Text Solution
Verified by ExpertsC
In the given complex
nickel is in +2 oxidation state and the ground state electronic configuration of
ions in free gaseous state is

For the given four coordinated complex to be paramagnetic, it must possess unpaired electrons in the valenc shell. To satisfy this condition, four lone pairs from the four ligands occupies the four
hybrid orbitals as

Therefore, geometry of paramagnetic complex must be tetrahedral. On the other hand, for complex to be diamagnetic, there should not be any unpaired electrons in the valence shell. This condition can be fulfilled by pairing electrons of
-orbitals against Hund's rule as

The above electronic arrangement gives
- hybridisation and therefore, square planar geometry to the complex.
Prepare Smarter with CGP Edu
Get practice questions, solutions, and test series in one place.
Write a Review
Share your experience with this question and solution.
Commentary
Send your comment, doubt, correction, or feedback to admin.
Similar Questions
Explore conceptually related problems