Home Physics JEE Main Full Syllabus Mock Test 75 Question New Syllabus TEST 3 PCM exhibits temperature dependent magnetic beh…
Physics JEE Main Full Syllabus Mock Test 75 Question New Syllabus TEST 3 PCM MCQ (Single Correct)

exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of in the paramagnetic and diamagnetic states respectively are

A
tetrahedral and tetrahedral
B
square planar and square planar
C
tetrahedral and square planar
D
square planar and tetrahedral

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Text Solution

Verified by Experts
The correct answer is:
C

In the given complex nickel is in +2 oxidation state and the ground state electronic configuration of ions in free gaseous state is

For the given four coordinated complex to be paramagnetic, it must possess unpaired electrons in the valenc shell. To satisfy this condition, four lone pairs from the four ligands occupies the four hybrid orbitals as

Therefore, geometry of paramagnetic complex must be tetrahedral. On the other hand, for complex to be diamagnetic, there should not be any unpaired electrons in the valence shell. This condition can be fulfilled by pairing electrons of -orbitals against Hund's rule as

The above electronic arrangement gives - hybridisation and therefore, square planar geometry to the complex.

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