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Chemistry Thermodynamics and Thermochemistry General Single Correct MCQ
Published on: August 14, 2026

At 298 K, change in internal energy for the complete combustion of fullerene, C 60 (s), an allotrope of carbon, and the enthalpy of formation of CO 2 (g) are –25970 kJ mol –1 and –393 kJ mol –1 respectively. The enthalpy of formation of C 60 (s) at 298 K is

A
–2390 kJ
B
4.95 × 10 4 kJ
C
2.60 × 10 4 kJ
D
2390 kJ

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The correct answer is:
D

C 60 (s) + 60 O 2 (g) 60 CO 2 (g) Δ U = –25970 kJ/mole.

Δ H = Δ U + Δ n g RT

= –25970 kJ/mole

Δ H rxn = 60 Δ H ƒ (CO 2 , g) – Δ H ƒ (C 60,S ) – 60 Δ H ƒ (O 2 , g)

–25970 = 60(–393) – Δ H ƒ (C 60 )

Δ H ƒ (C 60 ) = 60(–393) + 25970

= 2390 kJ

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