Home Chemistry Thermodynamics and Thermochemistry General 2.0 L of N 2 gas kept at 25ºC and 5 atm pres…
Chemistry Thermodynamics and Thermochemistry General Single Correct MCQ
Published on: August 14, 2026

2.0 L of N 2 gas kept at 25ºC and 5 atm pressure were expanded isothermally against a constant pressure of 1 atm until the pressure of the gas reaches 1 atm. Assuming ideal behavior, reversible work of expansion in this process (in J) is close to

A
810 J
B
–194 kJ
C
– 810 kJ
D
None

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Text Solution

Verified by Experts
The correct answer is:
D

w = –nRT ln

= – (2 × 5) × 2.303 log

= –16.121 lt atm

= –16.121 × 101.3 = –1633 J

w = –P ext (V 2 – V 1 )

=

= = –2 × 5 × L atm

= –810 J

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