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CGP EDU Academic Team
Published on: September 12, 2026
The electron in a hydrogen atom makes a transition n 1 → n 2 , where n 1 and n 2 are the principal quantum numbers of the two energy states. Assume the Bohr’s model to be valid. The time period of the electron in initial state is eight times that in the final state. What are the possible values of n 1 and n 2 ?
Text Solution
Verified by ExpertsThe correct answer is:
C
According to Bohr's model, the time period (T) of an electron in an orbit is given by:
$$ T_n = \frac{2\pi}{v_n} = 2\pi \sqrt{\frac{m r_n^3}{k_e e^2}} $$
and the radius (r) of the orbit is given by:
$$ r_n = n^2 \frac{h^2}{4\pi^2 m e^2} $$
Therefore, we can express the time period as:
$$ T_n \propto n^3 $$
If we assume the relation between the time periods in two different states is:
$$ \frac{T_{n_1}}{T_{n_2}} = \left( \frac{n_1}{n_2} \right)^3 $$
Given that the time period of the electron in the initial state (n_1) is eight times that in the final state (n_2), we have:
$$ T_{n_1} = 8 T_{n_2} $$
Substituting into our relation yields:
$$ \frac{T_{n_1}}{T_{n_2}} = 8 = \left( \frac{n_1}{n_2} \right)^3 $$
Taking the cube root gives:
$$ \frac{n_1}{n_2} = 2 $$
Therefore, if we let n_2 = n, we have n_1 = 2n.
The possible integer values for n_1 and n_2 that satisfy the principal quantum number conditions are:
- If n_2 = 1, then n_1 = 2 * 1 = 2
- If n_2 = 2, then n_1 = 2 * 2 = 4
Hence, the possible pairs (n_1, n_2) are (2, 1) and (4, 2).
The only valid transition allowed under quantum mechanics for hydrogen is (2, 1). Therefore, options C = (2, 1) is the only valid transition.
$$ T_n = \frac{2\pi}{v_n} = 2\pi \sqrt{\frac{m r_n^3}{k_e e^2}} $$
and the radius (r) of the orbit is given by:
$$ r_n = n^2 \frac{h^2}{4\pi^2 m e^2} $$
Therefore, we can express the time period as:
$$ T_n \propto n^3 $$
If we assume the relation between the time periods in two different states is:
$$ \frac{T_{n_1}}{T_{n_2}} = \left( \frac{n_1}{n_2} \right)^3 $$
Given that the time period of the electron in the initial state (n_1) is eight times that in the final state (n_2), we have:
$$ T_{n_1} = 8 T_{n_2} $$
Substituting into our relation yields:
$$ \frac{T_{n_1}}{T_{n_2}} = 8 = \left( \frac{n_1}{n_2} \right)^3 $$
Taking the cube root gives:
$$ \frac{n_1}{n_2} = 2 $$
Therefore, if we let n_2 = n, we have n_1 = 2n.
The possible integer values for n_1 and n_2 that satisfy the principal quantum number conditions are:
- If n_2 = 1, then n_1 = 2 * 1 = 2
- If n_2 = 2, then n_1 = 2 * 2 = 4
Hence, the possible pairs (n_1, n_2) are (2, 1) and (4, 2).
The only valid transition allowed under quantum mechanics for hydrogen is (2, 1). Therefore, options C = (2, 1) is the only valid transition.
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