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CGP EDU Academic Team
Published on: September 12, 2026
The maximum number of stereoisomer possible for the ion
is
Text Solution
Verified by ExpertsThe correct answer is:
B
To determine the maximum number of stereoisomers for the complex ion \[ [Pd(NH_3)_2(H_2O)_2Br_2]^{2+} \], we first analyze its structure based on coordination chemistry principles.
1. **Identify Coordination Number**: The palladium ion (Pd) in this complex has a coordination number of 6 since it is coordinated to 2 ammonia (NH3) ligands, 2 water (H2O) ligands, and 2 bromide (Br) ligands.
2. **Determine Geometry**: A coordination number of 6 typically leads to an octahedral geometry.
3. **Identify Possible Arrangements**: In an octahedral complex with 6 ligands, we can have different arrangements. The two types of geometric isomers we consider here are:
- **Facial (fac)**: where three identical ligands occupy one face of the octahedron.
- **Meridional (mer)**: where the three identical ligands are arranged along the meridian of the octahedron.
In our case, we have the following ligands:
- NH3 (2)
- H2O (2)
- Br (2)
Therefore, considering the different arrangements of these ligands:
- For **fac isomers**, there are 2 (since each type of ligand can be on one of the three faces).
- For **mer isomers**, there are 1 (as they are dictated by the structure).
4. **Count Stereoisomers**: Using the formula for the number of stereoisomers of octahedral complexes, we have: \[ ext{Number of Stereoisomers} = 2n \] where n is the number of different bidentate ligands. Here we have 3 types of ligands, thus this leads to a maximum of 6 stereoisomers.
Therefore, the maximum number of stereoisomers possible for \[ [Pd(NH_3)_2(H_2O)_2Br_2]^{2+} \] is 6, corresponding to option B.
1. **Identify Coordination Number**: The palladium ion (Pd) in this complex has a coordination number of 6 since it is coordinated to 2 ammonia (NH3) ligands, 2 water (H2O) ligands, and 2 bromide (Br) ligands.
2. **Determine Geometry**: A coordination number of 6 typically leads to an octahedral geometry.
3. **Identify Possible Arrangements**: In an octahedral complex with 6 ligands, we can have different arrangements. The two types of geometric isomers we consider here are:
- **Facial (fac)**: where three identical ligands occupy one face of the octahedron.
- **Meridional (mer)**: where the three identical ligands are arranged along the meridian of the octahedron.
In our case, we have the following ligands:
- NH3 (2)
- H2O (2)
- Br (2)
Therefore, considering the different arrangements of these ligands:
- For **fac isomers**, there are 2 (since each type of ligand can be on one of the three faces).
- For **mer isomers**, there are 1 (as they are dictated by the structure).
4. **Count Stereoisomers**: Using the formula for the number of stereoisomers of octahedral complexes, we have: \[ ext{Number of Stereoisomers} = 2n \] where n is the number of different bidentate ligands. Here we have 3 types of ligands, thus this leads to a maximum of 6 stereoisomers.
Therefore, the maximum number of stereoisomers possible for \[ [Pd(NH_3)_2(H_2O)_2Br_2]^{2+} \] is 6, corresponding to option B.
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