Physics Thermometry, Thermal Expansion and Calorimetry JEE Main 2025 - ( Thermal Properties of Matter ) MCQ (Single Correct)

Two liquids and have and as contact angles in a capillary tube. If , then identify the correct statement:

A
K is negative, then liquid A and liquid B have convex meniscus.
B
is negative, then liquid and liquid have concave meniscus.
C
K is zero, then liquid A has convex meniscus and liquid has concave meniscus.
D
K is negative, then liquid A has concave meniscus and liquid has convex

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The correct answer is:
D

The contact angle, , of a liquid in a capillary tube determines its meniscus shape:

If , then and the liquid wets the tube, giving a concave meniscus.

If , then and the liquid is nonwetting, resulting in a convex meniscus.

If , then and the meniscus is essentially flat.

We are given the ratio:

For to be negative:

The numerator and denominator must have opposite signs.

This means one of the liquids has (concave meniscus) and the other has (convex meniscus).

Consider Option D:
It states that if is negative, then liquid A has a concave meniscus (so ) and liquid B has a convex meniscus (so ).

Hence, the ratio becomes negative:

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