The correct statement regarding the basicity of arylamines is
A
Arylamines are generally less basic than alkylamines because lone-pair electrons in nitrogen are delocalized by interaction with the aromatic ring 
-electron system.
-electron system.
B
Arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalized by interaction with the aromatic ring 
-electron system.
-electron system.
C
Arylamines are generally more basic than alkylamines because of aryl group.
D
Arylamines are generally more basic than alkylamine because the nitrogen atom in arylamine is 
-hybridised.
-hybridised.
Text Solution
Verified by ExpertsThe correct answer is:
A
Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring 
-electron system.
Lone pair of nitrogen is in conjugation with the benzene ring which decreases the availability of electrons on nitrogen hence the basic strength decreases.
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