When a hot liquid is kept in a big room, the liquid will loose its temperature with time. The

thermal energy emitted by the liquid will be gained by the walls of the room. As the room is big, we can assume that the temperature difference between the room and the liquid is large. From Stephen's law, the liquid emits thermal energy in proportion to , where is the initial temperature of the liquid.
As the temperature decreases, the rate of loss of thermal energy will also decrease. So, the slope of the curve will also decrease.
Therefore, the plot of temperature with time is best represented by the curve .